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51.
Volunteered geographic information (VGI) is the assembly of spatial information based on public input. While VGI has proliferated in recent years, assessing the quality of volunteer-contributed data has proven challenging, leading some to question the efficiency of such programs. In this paper, we compare several quality metrics for individual volunteers’ contributions. The data were the product of the ‘Cropland Capture’ game, in which several thousand volunteers assessed 165,000 images for the presence of cropland over the course of 6 months. We compared agreement between volunteer ratings and an image's majority classification with volunteer self-agreement on repeated images and expert evaluations. We also examined the impact of experience and learning on performance. Volunteer self-agreement was nearly always higher than agreement with majority classifications, and much greater than agreement with expert validations although these metrics were all positively correlated. Volunteer quality showed a broad trend toward improvement with experience, but the highest accuracies were achieved by a handful of moderately active contributors, not the most active volunteers. Our results emphasize the importance of a universal set of expert-validated tasks as a gold standard for evaluating VGI quality.  相似文献   
52.
53.
Stilbite is locally present as a very late mineral on fractures and fissures of granitic basement in the Central Swiss Alps. Stilbite samples from the Gotthard rail base tunnel provide evidence that they originally formed as a K-absent variety at depth. However, all stilbite samples from surface outcrops above the tunnel display significant potassium concentrations. Interestingly, water from fractures in the tunnel (at 50 °C) is oversaturated with respect to stilbite and essentially potassium-free whereas waters from high-Alpine brooks above the tunnel (and at other high-Alpine areas) have unusually high K/Na ratios. The data suggest that stilbite that may actively form on fissures at tunnel level as a K-absent variety by precipitation from water. Older stilbite that originally formed as coatings on fracture walls was gradually exhumed and uplifted and finally reached the today’s erosion surface about 2,000 m above the tunnel. However, the stilbite reaches the erosion surface as a K-rich variety as a result of interaction of the original low-K stilbite with surface water and near-surface groundwater. This leads to the conclusion that minerals once formed at depth may significantly change their composition once they reach the ground water zone on their way to the erosion surface. In the case of the stilbite, if surface outcrops would have been the only source of samples and data, the K-rich composition could have been mistaken for the composition of the mineral when it formed, which is not the case. Late-stage compositional readjustments may be difficult to discern in samples from surface outcrops. The provided data show that original mineral compositions may be adjusted by late-stage water–rock interaction in a highly selective way.  相似文献   
54.
We investigate the dynamics of putative Earth-mass planets in the habitable zone (HZ) of the extrasolar planetary system OGLE-2006-BLG-109L, a close analogue of the Solar system. Our work is inspired by the work of Malhotra & Minton. Using the linear Laplace–Lagrange theory, they identified a strong secular resonance that may excite large eccentricity of orbits in the HZ. However, due to uncertain or unconstrained orbital parameters, the subsystem of Jupiters may be found in a dynamically active region of the phase space spanned by low-order mean-motion resonances. To generalize this secular model, we construct a semi-analytical averaging method in terms of the restricted problem. The secular orbits of large planets are approximated by numerically averaged osculating elements. They are used to calculate the mean orbits of terrestrial planets by means of a high-order analytic secular theory developed in our previous works. We found regions in the parameter space of the problem in which stable, quasi-circular orbits in the HZ are permitted. The excitation of eccentricity in the HZ strongly depends on the apsidal angle of jovian orbits. For some combinations of that angle, eccentricities and semimajor axes consistent with the observations, a terrestrial planet may survive in low eccentric orbits. We also study the effect of post-Newtonian gravity correction on the innermost secular resonance.  相似文献   
55.
Multiphase flow processes in unsaturated cohesive soils are often affected by deformation due to swelling and shrinking as a result of varying water contents. This paper presents a model concept which is denoted ‘phenomenological’ in terms of the processes responsible for soil deformation, since the effects of deformation on flow and transport are only considered by constitutive relations that allow an adaptation of the hydraulic properties. This new model is validated in a detailed intercomparison study with two state-of-the-art models that are capable of explicitly describing the processes relevant for the deformation. A ‘numerical experiment’ with a state-of-the-art reference model is used to produce ‘measurement data’ for an inverse-modelling-based estimation of the model input parameters for the phenomenological concept.  相似文献   
56.
Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.  相似文献   
57.
Surface elevation and current records contain non-tidal variance, often dismissed as noise. The processes responsible for the non-tidal component may also modulate the tidal signal, altering its strength and frequency structure. Because of their manner of generation and propagation, internal tides are inherently irregular. The non-stationary character of these and other tidal processes provides an integral and useful property of tidal records, because it provides an opportunity to obtain insights into tidal dynamics and the interaction of tidal and non-tidal processes. It is, moreover, productive to use multiple approaches in analyzing coastal and estuarine tidal processes so that both the time-varying and average frequency content are determined. Only by confronting the causes of non-stationary behaviour in this way can some of the remaining challenges in tidal analysis and prediction be overcome, e.g. shelf and estuarine currents, river tides, internal tides, tide-surge interactions and tidally influenced ecological processes. Several examples illustrate the utility of non-stationary tidal analysis methods.Responsible Editor: Jens Kappenberg  相似文献   
58.
Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   
59.
ABSTRACT

Ertsen discusses the representation of reality and uncertainty in our paper, raising three critical points. In response to the first, we agree that discussion of different interpretations of the concept of uncertainty is important when developing perceptual models – making different uncertainty interpretations explicit was a key motivation behind our method. Secondly, we do not, as Ertsen suggests, deny anyone who is not a “certified” scientist to have relevant knowledge. The elicitation of diverse views by discussing perceptual models is a basis for open discussion and decision making. Thirdly, Ertsen suggests that it is not useful to treat socio-hydrological systems as if they exist. We argue that we act as “pragmatic realists” in most practical applications by treating socio-hydrological systems as an external reality that can be known. But the uncertainty that arises from our knowledge limitations needs to be recognized, as it may impact on practical decision making and associated costs.  相似文献   
60.
Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.  相似文献   
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